分析化學(xué)和定量分析(英文版)
作者:(美)哈格,(美)卡爾 著
出版時間:2012年版
內(nèi)容簡介
本教材層次分明,條理清楚,闡述了定量分析化學(xué)、分析實驗室及分析研究的科學(xué)理論的概念,理論與實際相結(jié)合,符合人才培養(yǎng)目標(biāo)及課程教學(xué)的要求。書中對各部分知識歸納總結(jié)得很好,分類明確,由淺入深,適合于各個層次的讀者。對于教師來說,這本書也可以當(dāng)做很好的教材,編寫靈活,適合多種教學(xué)方式。這本教材的編寫比較有特色,它采用了先提出問題的方式,學(xué)生帶著問題去學(xué)習(xí)基礎(chǔ)理論,讓學(xué)生認識到每種分析方法的價值和用途。在講解過程中穿插習(xí)題,讓學(xué)生很快地將理論知識用于為解決實際問題所設(shè)計的“挑戰(zhàn)性問題”和“討論與報告”部分,進一步提高了學(xué)生的創(chuàng)新能力和開放性研究能力,對于學(xué)生綜合素質(zhì)的提高比較有幫助?!〗滩膬?nèi)容主要包括實驗玻璃器具、實驗記錄本和對實驗數(shù)據(jù)進行評價和對比,綜述了化學(xué)平衡中的基礎(chǔ)問題,并用基礎(chǔ)知識來說明經(jīng)典分析方法,如重量分析法、滴定法的原理和適當(dāng)?shù)膽?yīng)用,同時也引導(dǎo)學(xué)生學(xué)習(xí)一些常見的儀器分析技術(shù),像光譜學(xué)、色譜學(xué)和電化學(xué)方法。本教材的每一章都安排有幾個小組,每個小組有常見的問題。這種設(shè)計可以使讀者用多種方式從一個主題瀏覽到另一個主題,比如,一個學(xué)生需要化學(xué)平衡和相關(guān)計算的訓(xùn)練,他可以在第6章第3節(jié)中學(xué)習(xí)這部分知識。然而,那些對這部分知識已經(jīng)有很好基礎(chǔ)的同學(xué)可以跳到后面的章節(jié)來學(xué)習(xí)其他分析技術(shù),比如重量分析法和滴定法。如果教師想在講經(jīng)典分析方法前先介紹一些儀器分析方法的話,可以利用前幾章介紹一下化學(xué)分析的大體背景,然后再介紹電化學(xué)、光譜學(xué)或者色譜學(xué)。我們認為這個版本給了教師在運用這本書時最大的靈活性,不管他是用一學(xué)期來講解分析化學(xué),還是用傳統(tǒng)的兩學(xué)期中的一部分以先講定量分析,后講儀器分析的順序來講授。
目錄
Chapter 1 An Overview of Analytical Chemistry
1.1 Introduction: The Case of the Mysterious Chemist
1.2 The History of Chemical Analysis
1.2 A Origins of Chemical Analysis
1.2 B Chemical Analysis in the Modern World
1.3 General Terms Used in Chemical Analysis
1.3 A Sample-Related Terms
1.3 B Method-Related Terms
1.4 Information Provided by Chemical Analysis
1.5 Overview of Text
Key Words
Other Terrns
Questions
References
Chapter 2 Good Laboratory Practices
2.1 Introduction: A Question of Quality
2.1 A What Are Good Laboratory Practices?
2.1 B Establishing Good Laboratory Practices
BOX 2.1 : The Polymerase Chain Reaction
2.2 Laboratory Safety
2.2 A Common Components of Laboratory Safety
2.2 B Identifying Chemical Hazards
BOX 2.2 : Detemining the Safety of Chemicals
2.2 C Sources of Information on Chemicals
2.2 D Proper Handling of Chemicals
2.3 The Laboratory Notebook
2.3 A Recommended Notebook Practices
2.3 B Electronic Notebooks and Spreadsheets
2.4 Reporting Experimental Data
2.4 A The SI System of Measurements
2.4 B Significant Figures
Key Words 31
Other Terms 31
Questions
References
Chapter 3 Mass and Volume Measurements
3.1 Introduction: J. J. Berzelius
3.2 Mass Measurements
3.2 A The Determination of Mass
3.2 B Types of Laboratory Balances
BOX 3.1 : Atomic Force Microscopy
3.2 C Recommended Procedures for Mass Measurements
3.3 Volume Measurements
3.3 A The Determination of Volume
3.3 B Types of Volumetric Equipment
3.3 C Recommended Procedures for Volume Measurements
3.4 Samples, Reagents, and Solutions
3.4 A Describing Sample and Reagent Composition
3.4 B Solution Preparation
Key Words 58
Other Terms
References
Chapter 4 Making Decisions with Data
4.1 Introduction: Take Me Out to the Ball Game?
4.1 A Types of Laboratory Errors
4.1 B Accuracy and Precision
4.2 Describing Experimental Results
4.2 A Determining the Most Representative Value
4.2 B Reporting the Variation in a Group of Results
4.3 The Propagation of Errors
4.3 A Addition and Subtraction
4.3 B Multiplication and Division
4.3 C Logarithms, Antilogarithms, and Exponents
4.3 D Mixed Calculations
4.4 Sample Distributions and Confidence Intervals
4.4 A Describing the Variation in Large Data Sets
4.4 B Describing the Variation in Small Data Sets
BOX4.1 Who Was "Student"?
4.5 Comparing Experimental Results
4.5 A General Requirements for the Comparison of Data
4.5 B Comparing an Experimental Result with a Reference Value
4.5 C Comparing Two or More Experimental Results
BOX 4.2 Selecting a Confidence Level
4.5 D Comparing the Variation in Results
4.6 Detecting Outliers
4.6 A General Strategy in Handling Outliers
4.6 B Statistical Tests for Outliers
4.7 Fitting Experimental Results
4.7 A Linear Regression
4.7 B Testing the Goodness of a Fit
Chapter 5 Characterization and Selection of Analytical Methods
5.1 Introduction: The Vinland Map
5.2 Method Characterization and Validation
5.2 AAccuracy and Precision
BOX 5.1 :A Claser Look at Small Samples
……
Chapter 6 Chemical Activity and Chemical Equilibrium
Chapter 7 Chemical Solubility and Precipitation
Chapter 8 Acid-Base Reactions
Chapter 9 Complex Formation
Chapter 10 Oxidation-Reduction Reactions
Chapter 11 GravimetricAnalysis
Chapter 12 Acid-Base Titrations
Chapter 13 Complexometric and Precipitation Titrations
Chapter 14 An Introduction to Electrochemical Analysis
Chapter 15 RedoxTitrations
Chapter 16 Coulometry, Voltammetry, and Related Methods
Chapter 17 An Introduction to Spectroscopy
Chapter 18 Molecular Spectroscopy
Chapter 19 Atomic Spectroscopy
Chapter 20 An Introduction to Chemical Separations
Chapter 21 Gas Chromatography
Chapter 22 Liquid Chromatography
Chapter 23 Electrophoresis
Appendices
Answers to Selected Questions
Glossary
Index